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We can expect these differences to be quite pronounced, because rubidium and strontium have different chemical affinities: as we have noted, rubidium substitutes for potassium, and strontium for calcium.

About half the time this will produce a straight line with negative slope: that is, it will slope down from left to right instead of up.

In the reasoning that follows, the reader may recognize a sort of family resemblance to the reasoning behind step heating in the Ar-Ar method, although the two are not exactly alike.

When an igneous rock is first formed, its minerals will contain varying concentrations of rubidium and strontium, with some minerals being high in rubidium and low in strontium, others being high in strontium and low in rubidium.

As rubidium easily substitutes chemically for potassium, it can be found doing so in small quantities in potassium-containing minerals such as biotite, potassium feldspar, and hornblende.